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タイトル
  • ja Facilitation of the reduction of Pd(II) by the glass surface : Development of a glass-supported palladium catalyst
作成者
    • Nishiwaki, Nagatoshi
    • Mori, Yasuyuki
    • Fukuoka, Erina
    • Asahara, Haruyasu
    • Hirao, Shotaro
    • Sawayama, Jun
    • Saigo, Kazuhiko
    • Konishi, Tomoya
    • Shimoda, Masahiko
主題
  • Other Supported Catalyst
  • Other Glass
  • Other Nanoparticles
  • Other Palladium
  • Other Hydroxy Group
内容注記
  • Other A glass-supported palladium catalyst was developed. The catalyst could be used repeatedly (12 times) with a low catalytic loading (0.05 mol%) for the Heck reaction with a turnover number of 45 000, and no special treatment was necessary before catalyst reuse. The catalytic activity was maintained even after the catalyst was left to stand in air for one month. Furthermore, it was found that the glass surface assisted the adsorption and reduction of the Pd(II) species, through which catalytically active Pd(0) nanoparticles were formed and stabilized.
出版者 Elsevier B.V.
日付
    Created2019-02-13 , Issued2014-07
言語
  • eng
資源タイプ journal article
出版タイプ AM
資源識別子 URI http://hdl.handle.net/10173/1497
関連
  • isIdenticalTo DOI https://doi.org/10.1016/j.cplett.2014.06.005
収録誌情報
    • ISSN 0009-2614
      • Chemical Physics Letters
      • 608 開始ページ340 終了ページ343
ファイル
コンテンツ更新日時 2023-04-16