| タイトル |
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Facilitation of the reduction of Pd(II) by the glass surface : Development of a glass-supported palladium catalyst
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| 作成者 |
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| 主題 |
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Supported Catalyst
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Other
Glass
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Other
Nanoparticles
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Other
Palladium
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Hydroxy Group
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| 内容注記 |
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Other
A glass-supported palladium catalyst was developed. The catalyst could be used repeatedly (12 times) with a low catalytic loading (0.05 mol%) for the Heck reaction with a turnover number of 45 000, and no special treatment was necessary before catalyst reuse. The catalytic activity was maintained even after the catalyst was left to stand in air for one month. Furthermore, it was found that the glass surface assisted the adsorption and reduction of the Pd(II) species, through which catalytically active Pd(0) nanoparticles were formed and stabilized.
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| 出版者 |
Elsevier B.V.
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| 日付 |
Created2019-02-13
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Issued2014-07
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| 言語 |
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| 資源タイプ |
journal article |
| 出版タイプ |
AM |
| 資源識別子 |
URI
http://hdl.handle.net/10173/1497
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| 関連 |
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isIdenticalTo
DOI
https://doi.org/10.1016/j.cplett.2014.06.005
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| 収録誌情報 |
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Chemical Physics Letters
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巻608
開始ページ340
終了ページ343
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| ファイル |
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| コンテンツ更新日時 |
2023-04-16 |