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タイトル
  • en Synthesis and magnetic properties of ALnO2 (A = Cu or Ag; Ln = rare earths) with the delafossite structure
作成者
アクセス権 open access
主題
  • Other en Magnetic properties
  • Other en Rare earth
  • Other en Oxides
  • Other en Delafossite structure
  • Other en Magnetic susceptibility
  • NDC 431
内容注記
  • Abstract en Synthesis, structures, and magnetic properties of ternary rare earth oxides ALnO2. (A = Cu or Ag; Ln = rare earths) have been investigated. CuLnO2 (Ln = La, Pr, Nd, Sm, Eu) were synthesized by the direct solid state reaction of CU2O and Ln2O3, and AgLnO2 (Ln = Tm, Yb, Lu) were obtained by the cation-exchange reaction of NaLnO2 and AgNO3 in a KNO3 flux. These compounds crystallized in the delafossite-type structure with the rhombohedral 3R type (space group: R-3m). Magnetic susceptibility measurements showed that these compounds are paramagnetic down to 1.8 K. Specific heat measurements down to 0.4 K indicated that CuNdO2 ordered antiferromagnetically at 0.8 K.
出版者 en Elsevier Inc.
日付
    Issued2009-08
言語
  • eng
資源タイプ journal article
出版タイプ AM
資源識別子 HDL http://hdl.handle.net/2115/39191
関連
  • isVersionOf DOI https://doi.org/10.1016/j.jssc.2009.05.035
収録誌情報
    • PISSN 0022-4596
      • en Journal of Solid State Chemistry
      • 182 8 開始ページ2104 終了ページ2110
ファイル
コンテンツ更新日時 2023-07-26