タイトル |
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en
Improvement of a Real Gas-Sensor for the Origin of Methane Selectivity Degradation by mu-XAFS Investigation
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作成者 |
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アクセス権 |
open access |
権利情報 |
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主題 |
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Other
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Micro gas sensor
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Other
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Micro-XAFS
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Other
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Pd/Al2O3
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Other
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Deactivation
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NDC
501
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内容注記 |
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Abstract
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We have directly investigated the chemical state of the Pd species in a real mu-gas sensor device by examining the mu-fluorescence X-ray absorption fine structure. The mu-gas sensor device was heavily damaged by a heating process in which the temperature was ill-controlled, resulting in decrease of methane selectivity. We found that the PdO in the fresh mu-gas sensor was reduced to Pd metal particles as the methane selectivity decreased. Based on the investigation results, we modified the device structure so as to heat up homogeneously. The lifetime of the sensor was then successfully increased by more than 5 years.
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出版者 |
en
Springer
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日付 |
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言語 |
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資源タイプ |
journal article |
出版タイプ |
VoR |
資源識別子 |
HDL
http://hdl.handle.net/2115/59551
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関連 |
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isIdenticalTo
DOI
https://doi.org/10.1007/s40820-015-0035-7
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収録誌情報 |
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en
Nano-micro letters
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巻7
号3
開始ページ255
終了ページ260
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ファイル |
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コンテンツ更新日時 |
2023-07-26 |