| タイトル |
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Nitrobenzene-assisted reduction of phenylacetylene with hydrazine over nitrogen-doped metal-free activated carbon catalyst: Significance of interactions among substrates and catalyst
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| 作成者 |
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| アクセス権 |
open access |
| 権利情報 |
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© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
- http://creativecommons.org/licenses/by-nc-nd/4.0/
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
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| 主題 |
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Other
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Carbon
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Other
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Nitrogen doping
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Other
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Reduction
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Other
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Phenylacetylene
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Other
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Nitrobenzene
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NDC
430
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| 内容注記 |
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Abstract
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A nitrogen-doped activated carbon (AC) can catalyze the reduction of nitrobenzene with hydrazine but not phenylacetylene. When nitrobenzene coexists in the reaction mixture, however, phenylacetylene can also be reduced. Nitrobenzene is likely to assist the adsorption of phenylacetylene on the surface of AC catalyst through molecular interactions between the two substrates, allowing their simultaneous reduction to aniline and styrene. For these interactions to occur, nitrogen and/or oxygen species doped on the surface of AC are involved. The results demonstrate a new interesting catalytic function of nitrogen and oxygen-doped metal-free carbon materials. (C) 2016 Elsevier B.V. All rights reserved.
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| 出版者 |
en
Elsevier
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| 日付 |
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| 言語 |
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| 資源タイプ |
journal article |
| 出版タイプ |
AM |
| 資源識別子 |
HDL
http://hdl.handle.net/2115/71763
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| 関連 |
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isVersionOf
DOI
https://doi.org/10.1016/j.molcata.2016.06.022
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| 収録誌情報 |
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Journal of molecular catalysis a-chemical
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巻423
開始ページ181
終了ページ184
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| ファイル |
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| コンテンツ更新日時 |
2023-07-26 |
