タイトル |
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Magnetic Studies on Eu3MO7 (M = Nb, Ta, Ir) with Fluorite-related Structure by Eu-151 Mossbauer Spectroscopy and Magnetic Susceptibility Measurements
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作成者 |
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アクセス権 |
open access |
権利情報 |
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©2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
- http://creativecommons.org/licenses/by-nc-nd/4.0/
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
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主題 |
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Other
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Magnetic properties
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Other
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Europium
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Other
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Mossbauer spectrum
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Other
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Magnetic susceptibility
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NDC
430
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内容注記 |
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Abstract
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Magnetic properties of europium-containing compounds Eu3MO7 (M = Nb, Ta, Ir) with fluorite-related structure have been investigated. Magnetic susceptibility measurements show that all these compounds are paramagnetic and have no magnetic ordering down to 1.8 K. At very low temperatures (T < 50 K), the susceptibilities of each compound attain constant values, which is characteristic of the ground state for Eu3+ ions. The results of Eu-151 Mossbauer spectroscopic measurements show that the asymmetric parameter for Eu(2) in seven-coordination is much larger than that for Eu(1) in cubic environment, which in accordance with the crystallographic result.
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出版者 |
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Elsevier
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日付 |
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言語 |
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資源タイプ |
journal article |
出版タイプ |
AM |
資源識別子 |
HDL
http://hdl.handle.net/2115/78266
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関連 |
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isVersionOf
DOI
https://doi.org/10.1016/j.jssc.2018.03.024
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収録誌情報 |
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PISSN
0022-4596
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NCID
AA00707561
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en
Journal of solid state chemistry
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巻262
開始ページ224
終了ページ228
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ファイル |
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コンテンツ更新日時 |
2023-07-26 |