| タイトル |
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en
Radical reactions on interstellar icy dust grains: Experimental investigations of elementary processes
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| 作成者 |
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| アクセス権 |
metadata only access |
| 権利情報 |
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| 主題 |
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Other
en
chemical evolution
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Other
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molecular cloud
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Other
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cosmic dust
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Other
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radical–radical reaction
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Other
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surface reaction
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Other
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amorphous solid water
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NDC
440
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| 内容注記 |
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Abstract
en
Molecular clouds (MCs) in space are the birthplace of various molecular species. Chemical reactions occurring on the cryogenic surfaces of cosmic icy dust grains have been considered to play important roles in the formation of these species. Radical reactions are crucial because they often have low barriers and thus proceed even at low temperatures such as ∼10 K. Since the 2000s, laboratory experiments conducted under low-temperature, high-vacuum conditions that mimic MC environments have revealed the elementary physicochemical processes on icy dust grains. In this review, experiments conducted by our group in this context are explored, with a focus on radical reactions on the surface of icy dust analogues, leading to the formation of astronomically abundant molecules such as H2, H2O, H2CO, and CH3OH and deuterium fractionation processes. The development of highly sensitive, non-destructive methods for detecting adsorbates and their utilization for clarifying the behavior of free radicals on ice, which contribute to the formation of complex organic molecules, are also described.
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| 出版者 |
en
Japan Academy
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| 日付 |
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| 言語 |
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| 資源タイプ |
journal article |
| 出版タイプ |
NA |
| 資源識別子 |
HDL
http://hdl.handle.net/2115/89115
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| 関連 |
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isIdenticalTo
DOI
https://doi.org/10.2183/pjab.99.008
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| 収録誌情報 |
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en
Proceedings of the Japan Academy, Series B
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巻99
号4
開始ページ103
終了ページ130
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| コンテンツ更新日時 |
2023-07-26 |
