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Title
  • en Gas Chromatographic Equivalent Chain Length (ECL) Values of Fatty Acid Methyl Esters on a Highly Polar Ionic Liquid Column, SLB-IL111
Creator
    • en Nakamura, Yutarou
    • en Shimizu, Kana
Accessrights open access
Subject
  • Other en gas chromatography
  • Other en fatty acid
  • Other en ionic liquid
  • Other en SLB-IL111
  • Other en equivalent chain length
  • Other en fish oil
  • NDC 660
Description
  • Abstract en This paper reports the retention data of fatty acid methyl esters on a novel ionic liquid column, SLB-IL111, which has higher polarity than commercially available columns for gas chromatography (GC). The fatty acids analyzed using GC include branched-chain saturated fatty acids, C16-C22 monounsaturated fatty acid cis/trans and positional isomers, and polyunsaturated fatty acids commonly found in natural products. Fatty acids of sardine oil were also analyzed using GC. GC was carried out on a 100-m column under isothermal conditions within the range 120-170°C, using helium as a carrier gas. The retention data of fatty acid methyl esters were represented by equivalent chain length (ECL) values calculated from the retention times of each fatty acid related to those of saturated fatty acids with an even carbon number. This is novel information, obtained on an SLBIL111 column being operated at various temperatures with a single GC system. The results show that the column temperature greatly affected the ECL values of unsaturated fatty acids. Thus, when using this column for the analysis of fish oil fattya cids, it is necessary to precisely control the column temperature.
Publisher ja 北海道大学大学院水産科学研究院
Date
    Issued2014-03-14
Language
  • eng
Resource Type departmental bulletin paper
Version Type VoR
Identifier HDL http://hdl.handle.net/2115/54819
Journal
    • PISSN 1346-1842
    • NCID AA11547977
      • ja 北海道大学水産科学研究彙報
      • Volume Number64 Issue Number1 Page Start9 Page End16
File
    • fulltext p09-16.pdf
    • 960.82 KB (application/pdf)
      • Issued2014-03-14
Oaidate 2023-07-26