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タイトル	en POLYFLUOROALKYLATION OF CARBONYL COMPOUNDS BY POLYFLUOROALKYL ANIONS GENERATED FROM POLYFLUOROCARBOXAMIDES
作成者	en Wakita, Natshumi en Hara, Shoji NRID 1000020109490
アクセス権	open access
主題	NDC 430
内容注記	Abstract en Polyfluoroalkyl anions, generated by reduction of (polyfluoroalkanoyl)piperidines with Et3BHK, were used for the polyfluoroalkylation of carbonyl compounds. Trifluoromethylation of aromatic aldehydes proceeded in good yields, and that of aliphatic aldehydes afforded a moderate yield. In contrast, the yield was low when the reaction involved benzophenone. Pentafluoroethylation and octafluorobutylation of aldehydes were also carried out by using the corresponding (polyfluoroalkanoyl)piperidines, which were prepared from commercially available polyfluorocompounds. The (polyfluoroalkanoyDpiperidines were also prepared through polyfluorination, and were used in the polyfluoroalkylation of aldehydes.
出版者	en Pergamon-elsevier science ltd
日付	Issued2014-01-27
言語	eng
資源タイプ	journal article
出版タイプ	SMUR
資源識別子	HDL http://hdl.handle.net/2115/54926
関連	isVersionOf DOI https://doi.org/10.3987/COM-13-S(S)84
収録誌情報	PISSN 0385-5414 en Heterocycles 巻88 号2 開始ページ1201 終了ページ1212
ファイル	fulltext POLYFLUOROALKYLATION OF CARBONYL COMPOUNDS BY POLYFLUOROALKYL ANIONS GENERATED FROM POLYFLUOROCARBOXAMIDES.pdf 642.07 KB (application/pdf) Issued2014-01-27
コンテンツ更新日時	2023-07-26