| Title |
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Synthesis and magnetic properties of 12L-perovskites Ba4LnIr3O12 (Ln = lanthanides)
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| Creator |
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| Accessrights |
open access |
| Subject |
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Other
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Magnetic properties
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Other
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Lanthanides
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Other
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Perovskite
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Other
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Oxides
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Other
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Magnetic susceptibility
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Other
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Specific heat
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NDC
431
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| Description |
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Abstract
en
New quadruple perovskite oxides Ba4LnIr3O12 (Ln = lanthanides) were prepared and their magnetic properties were investigated. They crystallize in the monoclinic 12L-perovskite-type structure with space group C2/m. The Ir3O12 trimers and LnO6 octahedra are alternately linked by corner-sharing and form the perovskite-type structure with 12 layers. The Ln and Ir ions are both in the tetravalent state for Ln = Ce, Pr, and Tb compounds (Ba4Ln^[4+]Ir^[4+]3O12), and for other compounds (Ln = La, Nd, Sm-Gd, Dy-Lu), Ln ions are in the trivalent state and the mean oxidation state of Ir ions is +4.33(Ba4Ln^[3+]Ir^[4.33+]3O12). An antiferromagnetic transition has been observed for Ln = Ce, Pr, and Tb compounds at 10.5, 35, and 16 K, respectively, while the other compounds are paramagnetic down to 1.8 K.
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| Publisher |
en
Elsevier Inc.
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| Date |
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| Language |
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| Resource Type |
journal article |
| Version Type |
AM |
| Identifier |
HDL
http://hdl.handle.net/2115/39663
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| Relation |
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isVersionOf
DOI
https://doi.org/10.1016/j.jssc.2009.07.056
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| Journal |
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Journal of Solid State Chemistry
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Volume Number182
Issue Number10
Page Start2873
Page End2879
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| File |
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| Oaidate |
2023-07-26 |
