Title |
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Electrochemical synthesis of methyl-3,5,7-trifluoroadamantane-1-carboxylate under recycling use of ionic liquid media
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Creator |
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Accessrights |
open access |
Subject |
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Other
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Electrochemical fluorination
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Other
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Adamantane
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Other
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Ionic liquid
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Other
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Pyridine-5HF
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Other
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Recycle
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NDC
431
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Description |
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Abstract
en
Methyl-3,5,7-trifluoroadamantane-1-carboxylate, a key intermediate for the synthesis of 1-amino-3,5,7-trifluoroadamantane (trifluoroamantadine), was synthesized by the electrochemical fluorination of methyl adamantane-1-caroxylate in pyridine-5HF under constant current conditions. After the reaction, the product was extracted from pyridine-5HF by hexane-CH2Cl2, and recovered pyridine-5HF was used repeatedly.
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Publisher |
en
Elsevier B.V.
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Date |
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Language |
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Resource Type |
journal article |
Version Type |
AM |
Identifier |
HDL
http://hdl.handle.net/2115/50058
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Relation |
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isVersionOf
DOI
https://doi.org/10.1016/j.jfluchem.2012.04.006
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Journal |
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Journal of Fluorine Chemistry
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Volume Number140
Page Start28
Page End30
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File |
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Oaidate |
2023-07-26 |