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Title
  • en A gold isocyanide complex with a pendant carboxy group: orthogonal molecular arrangements and hypsochromically shifted luminescent mechanochromism
Creator
Accessrights open access
Description
  • Abstract en The epistatic double hydrogen bonds that arise from the presence of a pendant carboxy group in a gold isocyanide complex result in strong aurophilic interactions in a magenta-emitting polymorph. This is due to the lack of the typically antiparallel dimer arrangements, which often prevent the formation of strong aurophilic interactions. Furthermore, this polymorph shows hypsochromically shifted luminescence mechanochromism.
Publisher en Royal Society of Chemistry
Date
    Issued2018-10-11
Language
  • eng
Resource Type journal article
Version Type AM
Identifier HDL http://hdl.handle.net/2115/75750
Relation
  • isVersionOf DOI https://doi.org/10.1039/c8cc06490c
Journal
    • PISSN 1359-7345
      • en Chemical communications
      • Volume Number54 Issue Number79 Page Start11136 Page End11139
File
Oaidate 2023-07-26